49, 1001 Cantrell, Christopher A Atmospheric Chemistry Division/NESL/NCAR HO2 and HO2+RO2 from PeRCIMS at Manitou Experimental Forest BEACHON-RoMBAS 1,1 2011, 08, 10, 2011, 11, 23 0 Start_MST, seconds, number_of_seconds_from_0000_MST 6 1,1,1,1,1,1 -99999,-99999,-99999,-99999,-99999,-99999 Stop_MST, seconds, number_of_seconds_from_0000_MST Mid_MST, seconds, number_of_seconds_from_0000_MST HO2, pptv, HO2_mixing_ratio HO2_uncertainty, pptv, HO2_2_sigma_uncertainty HO2+RO2, pptv, HO2+RO2_mixing_ratio HO2+RO2_uncertainty, pptv, HO2+RO2_2_sigma_uncertainty 5 These data are reduced using four factors determined in the laboratory and in the field: F_lo and F_hi are the radical sensitivities in the HO2+RO2 and HO2 modes, respectively (units pptv/ion ratio). Alpha_lo and alpha_hi are the ratios of RO2 to HO2 sensitivity in the HO2+RO2 and HO2 modes, respectively. HO2+RO2 concentrations are then S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo - 1)/(alpha_lo - alpha_hi) . HO2 concentrations are S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo)/(alpha_lo - alpha_hi) . S_lo is the background corrected ion ratio in the HO2+RO2 mode, and S_hi is the background corrected ion ratio in the HO2 mode. The ion ratios are mass 97 signal count rate minus background count rate divided by mass 62 count rate. 24 PI_CONTACT_INFO: 303-497-1479, NCAR, 3090 Center Green Dr., Boulder, CO 80301, cantrell@ucar.edu PLATFORM: Seacontainer #1 LOCATION: Manitou Experimental Forest, Woodland Park, Colorado, USA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: These data were collected using a CIMS based instrument. An inlet collects ambient air from the free air stream and adds reagents, includling O2 or N2 diluents, and NO and SO2 reagent gases. This method, called oxygen dilution modulation leads to nearly 100% measurement of HO2 and RO2 in the O2 dilution/low reagent concentration mode, whereas RO2 is measured with less than 15% efficiency in the N2 dilution/higher reagent concentration mode. This is because the chemistry converts peroxy radicals to H2SO4 efficiently in the O2 mode, but RO2 radicals are converted to RONO in the N2 mode. The H2SO4 thus produced is ionized by reaction with NO3- ions. The reagent and product ions are detected by mass spectrometry using quadrupole mass filtering and counting by a channel electron multiplier operating in the negative ion mode. DATA_INFO: Signal data for HO2+RO2 are collected during the 0-7 second time interval, and for HO2 in 30-37 second time interval. UNCERTAINTY: approximately 35% (2 sigma) for values well above 2 pptv; estimates are listed for each data point (2 sigma) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: N/A PROJECT_INFO: BEACHON-RoMBAS, 20-Jul-2011 to 30-Aug-2011 STIPULATIONS_ON_USE: contact PI BEFORE use/presentation/publication OTHER_COMMENTS: REVISION: R1; R0 R1: final data R0: preliminary data Start_MST,Stop_MST,Mid_MST,HO2,HO2_uncertainty,HO2+RO2,HO2+RO2_uncertainty 0,59,30,4.90,4.10,10.30,4.60 60,119,90,3.60,4.10,10.60,4.60 120,179,150,3.40,4.10,10.60,4.60 180,239,210,3.20,4.10,10.90,4.70 240,299,270,4.30,4.10,10.40,4.60 300,359,330,3.40,4.10,11.00,4.70 360,419,390,2.60,4.00,10.70,4.60 420,479,450,2.10,4.00,10.70,4.60 480,539,510,2.80,4.00,10.10,4.60 540,599,570,3.90,4.10,10.70,4.60 600,659,630,3.70,4.10,11.00,4.70 660,719,690,3.80,4.10,9.90,4.60 720,779,750,3.50,4.10,9.30,4.50 780,839,810,4.50,4.10,12.10,4.80 840,899,870,3.70,4.10,13.00,4.90 900,959,930,3.10,4.10,11.50,4.70 960,1019,990,2.90,4.10,9.30,4.50 1020,1079,1050,3.30,4.10,11.50,4.70 1080,1139,1110,4.70,4.10,13.90,5.00 1140,1199,1170,3.80,4.10,14.40,5.10 1200,1259,1230,3.20,4.10,13.40,5.00 1260,1319,1290,2.80,4.00,11.30,4.70 1320,1379,1350,5.30,4.20,10.10,4.60 1380,1439,1410,6.30,4.20,10.40,4.60 1440,1499,1470,5.60,4.20,11.40,4.70 1500,1559,1530,3.90,4.10,11.80,4.80 1560,1619,1590,3.70,4.10,11.50,4.70 1620,1679,1650,3.50,4.10,11.30,4.70 1680,1739,1710,3.40,4.10,11.70,4.80 1740,1799,1770,3.60,4.10,11.90,4.80 1800,1859,1830,3.00,4.10,11.00,4.70 1860,1919,1890,3.20,4.10,10.60,4.60 1920,1979,1950,2.60,4.00,9.00,4.50 1980,2039,2010,3.10,4.10,9.20,4.50 2040,2099,2070,2.90,4.00,8.10,4.40 2100,2159,2130,2.80,4.00,8.60,4.40 2160,2219,2190,3.30,4.10,9.10,4.50 2220,2279,2250,4.00,4.10,10.20,4.60 2280,2339,2310,4.00,4.10,9.70,4.50 2340,2399,2370,4.30,4.10,10.30,4.60 2400,2459,2430,3.40,4.10,10.10,4.60 2460,2519,2490,3.80,4.10,8.90,4.40 2520,2579,2550,3.90,4.10,8.80,4.40 2580,2639,2610,4.40,4.10,8.60,4.40 2640,2699,2670,4.30,4.10,9.70,4.50 2700,2759,2730,4.00,4.10,8.60,4.40 2760,2819,2790,4.20,4.10,9.00,4.50 2820,2879,2850,5.00,4.20,11.70,4.80 2880,2939,2910,5.30,4.20,13.90,5.00 2940,2999,2970,5.20,4.20,14.90,5.20 3000,3059,3030,4.20,4.10,14.10,5.10 3060,3119,3090,3.70,4.10,12.70,4.90 3120,3179,3150,3.60,4.10,10.60,4.60 3180,3239,3210,3.40,4.10,8.30,4.40 3240,3299,3270,3.60,4.10,7.10,4.30 3300,3359,3330,3.70,4.10,8.80,4.40 3360,3419,3390,4.20,4.10,11.20,4.70 3420,3479,3450,3.60,4.10,12.60,4.90 3480,3539,3510,3.10,4.10,10.40,4.60 3540,3599,3570,2.70,4.00,8.10,4.40 3600,3659,3630,2.40,4.00,5.40,4.20 3660,3719,3690,3.50,4.10,7.00,4.30 3720,3779,3750,3.40,4.10,7.30,4.30 3780,3839,3810,3.20,4.10,9.00,4.50 3840,3899,3870,2.40,4.00,7.50,4.30 3900,3959,3930,3.80,4.10,7.50,4.30 3960,4019,3990,4.90,4.10,7.60,4.30 4020,4079,4050,4.10,4.10,7.10,4.30 4080,4139,4110,2.80,4.00,7.50,4.30 4140,4199,4170,2.10,4.00,6.70,4.30 4200,4259,4230,2.50,4.00,8.10,4.40 4260,4319,4290,2.10,4.00,9.80,4.50 4320,4379,4350,1.40,4.00,10.90,4.70 4380,4439,4410,2.20,4.00,12.10,4.80 4440,4499,4470,2.40,4.00,9.60,4.50 4500,4559,4530,3.40,4.10,8.60,4.40 4560,4619,4590,3.10,4.10,6.50,4.30 4620,4679,4650,3.60,4.10,10.70,4.60 4680,4739,4710,3.60,4.10,13.70,5.00 4740,4799,4770,3.00,4.10,14.80,5.20 4800,4859,4830,2.00,4.00,8.60,4.40 4860,4919,4890,2.60,4.00,6.20,4.20 4920,4979,4950,2.60,4.00,4.70,4.10 4980,5039,5010,3.40,4.10,7.00,4.30 5040,5099,5070,1.90,4.00,6.20,4.20 5100,5159,5130,2.50,4.00,8.60,4.40 5160,5219,5190,2.60,4.00,11.60,4.70 5220,5279,5250,4.00,4.10,12.90,4.90 5280,5339,5310,3.60,4.10,13.60,5.00 5340,5399,5370,2.80,4.00,10.50,4.60 5400,5459,5430,1.60,4.00,10.90,4.70 5460,5519,5490,1.70,4.00,7.50,4.30 5520,5579,5550,3.30,4.10,7.90,4.40 5580,5639,5610,4.00,4.10,5.30,4.20 5640,5699,5670,3.80,4.10,8.10,4.40 5700,5759,5730,3.20,4.10,8.20,4.40 5760,5819,5790,4.20,4.10,8.30,4.40 5820,5879,5850,5.50,4.20,5.80,4.20 5880,5939,5910,6.70,4.30,5.80,4.20 5940,5999,5970,7.10,4.30,9.00,4.50 6000,6059,6030,6.40,4.20,10.70,4.60 6060,6119,6090,4.70,4.10,10.80,4.70 6120,6179,6150,1.70,4.00,8.60,4.40 6180,6239,6210,0.50,4.00,7.50,4.30 6240,6299,6270,1.30,4.00,8.20,4.40 6300,6359,6330,2.90,4.10,10.30,4.60 6360,6419,6390,4.20,4.10,10.40,4.60 6420,6479,6450,4.60,4.10,8.70,4.40 6480,6539,6510,4.80,4.10,7.30,4.30 6540,6599,6570,4.20,4.10,8.10,4.40 6600,6659,6630,4.10,4.10,8.90,4.50 6660,6719,6690,4.20,4.10,7.70,4.30 6720,6779,6750,5.30,4.20,8.20,4.40 6780,6839,6810,5.20,4.20,7.60,4.30 6840,6899,6870,4.40,4.10,8.80,4.40 6900,6959,6930,2.70,4.00,5.90,4.20 6960,7019,6990,2.70,4.00,5.80,4.20 7020,7079,7050,2.60,4.00,4.10,4.10 7080,7139,7110,3.80,4.10,7.20,4.30 7140,7199,7170,4.20,4.10,7.00,4.30 7200,7259,7230,5.30,4.20,9.90,4.60 7260,7319,7290,4.90,4.10,9.60,4.50 7320,7379,7350,3.70,4.10,11.20,4.70 7380,7439,7410,3.60,4.10,9.40,4.50 7440,7499,7470,3.90,4.10,8.10,4.40 7500,7559,7530,4.50,4.10,7.30,4.30 7560,7619,7590,4.20,4.10,8.20,4.40 7620,7679,7650,3.20,4.10,11.30,4.70 7680,7739,7710,2.50,4.00,12.90,4.90 7740,7799,7770,3.40,4.10,12.10,4.80 7800,7859,7830,3.40,4.10,9.00,4.50 7860,7919,7890,4.50,4.10,9.30,4.50 7920,7979,7950,2.00,4.00,9.20,4.50 7980,8039,8010,2.90,4.00,11.60,4.70 8040,8099,8070,2.90,4.00,12.10,4.80 8100,8159,8130,4.30,4.10,14.40,5.10 8160,8219,8190,4.10,4.10,12.20,4.80 8220,8279,8250,3.50,4.10,8.70,4.40 8280,8339,8310,3.00,4.10,7.30,4.30 8340,8399,8370,2.80,4.00,6.00,4.20 8400,8459,8430,3.00,4.10,8.00,4.40 8460,8519,8490,3.30,4.10,7.00,4.30 8520,8579,8550,3.60,4.10,10.70,4.60 8580,8639,8610,3.50,4.10,9.50,4.50 8640,8699,8670,2.70,4.00,7.30,4.30 8700,8759,8730,3.20,4.10,7.10,4.30 8760,8819,8790,3.60,4.10,6.20,4.20 8820,8879,8850,4.60,4.10,10.60,4.60 8880,8939,8910,2.90,4.10,8.40,4.40 8940,8999,8970,1.20,4.00,7.90,4.40 9000,9059,9030,0.60,4.00,4.90,4.10 9060,9119,9090,1.20,4.00,3.70,4.10 9120,9179,9150,2.00,4.00,3.40,4.10 9180,9239,9210,2.40,4.00,5.90,4.20 9240,9299,9270,2.10,4.00,6.40,4.20 9300,9359,9330,1.50,4.00,5.50,4.20 9360,9419,9390,2.60,4.00,4.70,4.10 9420,9479,9450,4.10,4.10,6.70,4.30 9480,9539,9510,4.50,4.10,8.90,4.40 9540,9599,9570,2.20,4.00,7.80,4.30 9600,9659,9630,0.00,4.00,4.00,4.10 9660,9719,9690,-0.30,4.00,2.20,4.00 9720,9779,9750,0.60,4.00,1.20,4.00 9780,9839,9810,1.50,4.00,2.00,4.00 9840,9899,9870,2.30,4.00,2.80,4.00 9900,9959,9930,2.40,4.00,2.70,4.00 9960,10019,9990,3.20,4.10,5.80,4.20 10020,10079,10050,3.40,4.10,7.40,4.30 10080,10139,10110,3.90,4.10,10.00,4.60 10140,10199,10170,3.50,4.10,9.00,4.50 10200,10259,10230,2.30,4.00,10.50,4.60 10260,10319,10290,2.00,4.00,10.80,4.60 10320,10379,10350,0.50,4.00,10.70,4.60 10380,10439,10410,-0.20,4.00,8.70,4.40 10440,10499,10470,0.00,4.00,9.30,4.50 10500,10559,10530,2.00,4.00,11.60,4.70 10560,10619,10590,2.50,4.00,11.60,4.70 10620,10679,10650,2.90,4.10,13.20,4.90 10680,10739,10710,2.90,4.00,11.20,4.70 10740,10799,10770,4.20,4.10,11.40,4.70 10800,10859,10830,4.40,4.10,11.40,4.70 10860,10919,10890,2.60,4.00,9.40,4.50 10920,10979,10950,2.40,4.00,9.40,4.50 10980,11039,11010,2.20,4.00,7.80,4.30 11040,11099,11070,3.90,4.10,9.70,4.50 11100,11159,11130,4.70,4.10,10.10,4.60 11160,11219,11190,4.70,4.10,8.20,4.40 11220,11279,11250,4.60,4.10,8.60,4.40 11280,11339,11310,3.20,4.10,9.30,4.50 11340,11399,11370,2.50,4.00,9.90,4.60 11400,11459,11430,2.40,4.00,8.40,4.40 11460,11519,11490,3.60,4.10,7.30,4.30 11520,11579,11550,3.50,4.10,7.00,4.30 11580,11639,11610,2.70,4.00,7.40,4.30 11640,11699,11670,2.00,4.00,7.60,4.30 11700,11759,11730,1.70,4.00,7.60,4.30 11760,11819,11790,1.30,4.00,7.30,4.30 11820,11879,11850,0.40,4.00,6.60,4.30 11880,11939,11910,1.30,4.00,6.60,4.30 11940,11999,11970,1.80,4.00,6.50,4.20 12000,12059,12030,3.60,4.10,6.90,4.30 12060,12119,12090,3.60,4.10,6.30,4.20 12120,12179,12150,4.00,4.10,5.30,4.20 12180,12239,12210,3.10,4.10,4.10,4.10 12240,12299,12270,1.90,4.00,3.40,4.10 12300,12359,12330,0.50,4.00,3.90,4.10 12360,12419,12390,0.10,4.00,5.50,4.20 12420,12479,12450,1.00,4.00,8.20,4.40 12480,12539,12510,3.20,4.10,12.50,4.90 12540,12599,12570,3.30,4.10,14.80,5.20 12600,12659,12630,2.80,4.00,13.80,5.00 12660,12719,12690,2.00,4.00,13.30,5.00 12720,12779,12750,2.50,4.00,10.00,4.60 12780,12839,12810,2.60,4.00,12.20,4.80 12840,12899,12870,3.00,4.10,8.90,4.50 12900,12959,12930,3.90,4.10,12.50,4.90 12960,13019,12990,4.20,4.10,9.70,4.50 13020,13079,13050,3.50,4.10,10.50,4.60 13080,13139,13110,2.00,4.00,8.80,4.40 13140,13199,13170,1.30,4.00,10.20,4.60 13200,13259,13230,2.50,4.00,11.70,4.80 13260,13319,13290,2.00,4.00,11.50,4.70 13320,13379,13350,2.20,4.00,12.10,4.80 13380,13439,13410,1.70,4.00,9.40,4.50 13440,13499,13470,2.60,4.00,9.90,4.60 13500,13559,13530,3.40,4.10,9.60,4.50 13560,13619,13590,2.70,4.00,12.40,4.80 13620,13679,13650,2.70,4.00,12.20,4.80 13680,13739,13710,3.50,4.10,10.00,4.60 13740,13799,13770,4.40,4.10,6.90,4.30 13800,13859,13830,4.90,4.10,4.60,4.10 13860,13919,13890,3.60,4.10,3.90,4.10 13920,13979,13950,2.40,4.00,5.30,4.20 13980,14039,14010,1.80,4.00,7.00,4.30 14040,14099,14070,0.60,4.00,6.40,4.20 14100,14159,14130,1.20,4.00,5.50,4.20 14160,14219,14190,0.60,4.00,4.00,4.10 14220,14279,14250,3.20,4.10,7.50,4.30 14280,14339,14310,3.70,4.10,8.90,4.50 14340,14399,14370,4.70,4.10,10.60,4.60 14400,14459,14430,4.70,4.10,11.50,4.70 14460,14519,14490,3.30,4.10,10.60,4.60 14520,14579,14550,4.90,4.10,11.00,4.70 14580,14639,14610,4.80,4.10,9.70,4.50 14640,14699,14670,5.50,4.20,11.80,4.80 14700,14759,14730,3.90,4.10,10.80,4.70 14760,14819,14790,2.30,4.00,8.60,4.40 14820,14879,14850,3.80,4.10,8.40,4.40 14880,14939,14910,4.20,4.10,8.80,4.40 14940,14999,14970,4.90,4.10,12.20,4.80 15000,15059,15030,2.70,4.00,10.20,4.60 15060,15119,15090,1.80,4.00,10.20,4.60 15120,15179,15150,0.20,4.00,6.50,4.20 15180,15239,15210,1.30,4.00,6.30,4.20 15240,15299,15270,0.90,4.00,6.60,4.30 15300,15359,15330,2.20,4.00,9.10,4.50 15360,15419,15390,1.80,4.00,10.60,4.60 15420,15479,15450,3.10,4.10,10.60,4.60 15480,15539,15510,2.70,4.00,10.60,4.60 15540,15599,15570,2.40,4.00,8.70,4.40 15600,15659,15630,1.80,4.00,8.10,4.40 15660,15719,15690,3.00,4.10,8.60,4.40 15720,15779,15750,3.30,4.10,9.70,4.50 15780,15839,15810,2.90,4.00,8.70,4.40 15840,15899,15870,2.30,4.00,8.30,4.40 15900,15959,15930,3.20,4.10,10.40,4.60 15960,16019,15990,3.30,4.10,12.30,4.80 16020,16079,16050,4.10,4.10,13.30,5.00 16080,16139,16110,2.30,4.00,10.20,4.60 16140,16199,16170,2.70,4.00,11.60,4.70 16200,16259,16230,1.80,4.00,10.00,4.60 16260,16319,16290,3.10,4.10,10.00,4.60 16320,16379,16350,3.80,4.10,9.10,4.50 16380,16439,16410,4.10,4.10,8.10,4.40 16440,16499,16470,3.80,4.10,7.20,4.30 16500,16559,16530,3.10,4.10,7.10,4.30 16560,16619,16590,3.20,4.10,5.90,4.20 16620,16679,16650,4.10,4.10,7.50,4.30 16680,16739,16710,3.30,4.10,4.90,4.10 16740,16799,16770,2.50,4.00,9.80,4.50 16800,16859,16830,1.40,4.00,10.80,4.70 16860,16919,16890,2.50,4.00,11.80,4.80 16920,16979,16950,1.80,4.00,8.60,4.40 16980,17039,17010,1.80,4.00,8.70,4.40 17040,17099,17070,2.50,4.00,8.80,4.40 17100,17159,17130,3.80,4.10,10.10,4.60 17160,17219,17190,4.40,4.10,9.60,4.50 17220,17279,17250,4.20,4.10,8.80,4.40 17280,17339,17310,3.60,4.10,6.40,4.20 17340,17399,17370,3.00,4.10,5.90,4.20 17400,17459,17430,2.50,4.00,6.90,4.30 17460,17519,17490,2.40,4.00,9.50,4.50 17520,17579,17550,2.40,4.00,9.00,4.50 17580,17639,17610,2.00,4.00,10.00,4.60 17640,17699,17670,2.60,4.00,8.80,4.40 17700,17759,17730,3.00,4.10,8.60,4.40 17760,17819,17790,2.10,4.00,9.80,4.50 17820,17879,17850,0.80,4.00,8.10,4.40 17880,17939,17910,0.20,4.00,9.30,4.50 17940,17999,17970,1.80,4.00,8.00,4.40 18000,18059,18030,3.90,4.10,10.10,4.60 18060,18119,18090,4.90,4.10,11.80,4.80 18120,18179,18150,3.70,4.10,10.20,4.60 18180,18239,18210,3.00,4.10,9.90,4.60 18240,18299,18270,1.70,4.00,7.80,4.40 18300,18359,18330,2.60,4.00,10.80,4.70 18360,18419,18390,2.00,4.00,11.30,4.70 18420,18479,18450,2.20,4.00,9.80,4.50 18480,18539,18510,1.80,4.00,7.10,4.30 18540,18599,18570,1.90,4.00,5.80,4.20 18600,18659,18630,2.60,4.00,7.40,4.30 18660,18719,18690,2.80,4.00,6.40,4.20 18720,18779,18750,3.40,4.10,7.30,4.30 18780,18839,18810,2.70,4.00,8.50,4.40 18840,18899,18870,1.60,4.00,9.90,4.60 18900,18959,18930,1.90,4.00,9.50,4.50 18960,19019,18990,2.90,4.00,6.80,4.30 19020,19079,19050,4.20,4.10,6.90,4.30 19080,19139,19110,4.00,4.10,8.60,4.40 19140,19199,19170,3.80,4.10,9.70,4.50 19200,19259,19230,3.70,4.10,11.50,4.70 19260,19319,19290,2.80,4.00,9.20,4.50 19320,19379,19350,3.30,4.10,10.00,4.60 19380,19439,19410,2.70,4.00,7.60,4.30 19440,19499,19470,2.80,4.00,7.90,4.40 19500,19559,19530,1.60,4.00,7.80,4.40 19560,19619,19590,1.10,4.00,9.90,4.60 19620,19679,19650,1.10,4.00,11.80,4.80 19680,19739,19710,1.70,4.00,10.70,4.60 19740,19799,19770,3.10,4.10,9.00,4.50 19800,19859,19830,3.20,4.10,7.30,4.30 19860,19919,19890,3.10,4.10,8.30,4.40 19920,19979,19950,2.30,4.00,9.50,4.50 19980,20039,20010,1.60,4.00,8.70,4.40 20040,20099,20070,2.30,4.00,8.70,4.40 20100,20159,20130,4.10,4.10,9.90,4.50 20160,20219,20190,5.20,4.20,9.40,4.50 20220,20279,20250,4.90,4.10,7.70,4.30 20280,20339,20310,3.40,4.10,7.00,4.30 20340,20399,20370,2.30,4.00,7.70,4.30 20400,20459,20430,1.70,4.00,9.50,4.50 20460,20519,20490,1.60,4.00,6.80,4.30 20520,20579,20550,2.80,4.00,6.40,4.20 20580,20639,20610,2.40,4.00,5.30,4.20 20640,20699,20670,2.30,4.00,6.00,4.20 20700,20759,20730,2.00,4.00,7.50,4.30 20760,20819,20790,2.80,4.00,7.90,4.40 20820,20879,20850,2.80,4.00,6.80,4.30 20880,20939,20910,3.50,4.10,6.90,4.30 20940,20999,20970,3.80,4.10,8.80,4.40 21000,21059,21030,4.00,4.10,8.20,4.40 21060,21119,21090,3.10,4.10,6.40,4.20 21120,21179,21150,2.30,4.00,3.40,4.10 21180,21239,21210,2.30,4.00,6.60,4.30 21240,21299,21270,2.10,4.00,6.60,4.30 21300,21359,21330,1.10,4.00,9.20,4.50 21360,21419,21390,1.00,4.00,6.40,4.20 21420,21479,21450,1.80,4.00,8.10,4.40 21480,21539,21510,2.40,4.00,9.20,4.50 21540,21599,21570,0.70,4.00,12.70,4.90 21600,21659,21630,-0.10,4.00,13.90,5.00 21660,21719,21690,0.10,4.00,10.00,4.60 21720,21779,21750,2.30,4.00,8.30,4.40 21780,21839,21810,2.80,4.00,7.10,4.30 21840,21899,21870,3.30,4.10,9.00,4.50 21900,21959,21930,2.40,4.00,9.00,4.50 21960,22019,21990,0.90,4.00,8.10,4.40 22020,22079,22050,0.50,4.00,9.80,4.50 22080,22139,22110,1.00,4.00,10.00,4.60 22140,22199,22170,3.10,4.10,9.50,4.50 22200,22259,22230,2.90,4.00,6.70,4.30 22260,22319,22290,2.80,4.00,7.20,4.30 22320,22379,22350,1.80,4.00,7.70,4.30 22380,22439,22410,3.20,4.10,8.10,4.40 22440,22499,22470,3.20,4.10,7.80,4.40 22500,22559,22530,2.60,4.00,6.20,4.20 22560,22619,22590,1.30,4.00,7.10,4.30 22620,22679,22650,1.50,4.00,6.20,4.20 22680,22739,22710,2.20,4.00,6.30,4.20 22740,22799,22770,1.90,4.00,3.60,4.10 22800,22859,22830,1.30,4.00,5.50,4.20 22860,22919,22890,1.20,4.00,7.00,4.30 22920,22979,22950,0.70,4.00,8.60,4.40 22980,23039,23010,0.90,4.00,6.60,4.30 23040,23099,23070,0.30,4.00,10.40,4.60 23100,23159,23130,1.90,4.00,12.30,4.80 23160,23219,23190,1.10,4.00,12.10,4.80 23220,23279,23250,1.40,4.00,6.80,4.30 23280,23339,23310,1.70,4.00,5.50,4.20 23340,23399,23370,1.90,4.00,5.20,4.20 23400,23459,23430,1.30,4.00,7.40,4.30 23460,23519,23490,0.40,4.00,10.10,4.60 23520,23579,23550,0.90,4.00,13.80,5.00 23580,23639,23610,2.00,4.00,13.30,5.00 23640,23699,23670,2.00,4.00,9.10,4.50 23700,23759,23730,2.60,4.00,4.50,4.10 23760,23819,23790,3.00,4.10,3.80,4.10 23820,23879,23850,2.60,4.00,4.60,4.10 23880,23939,23910,2.20,4.00,9.60,4.50 23940,23999,23970,1.00,4.00,9.20,4.50 24000,24059,24030,2.70,4.00,12.30,4.80 24060,24119,24090,2.80,4.00,9.80,4.50 24120,24179,24150,3.00,4.10,13.00,4.90 24180,24239,24210,1.30,4.00,8.90,4.50 24240,24299,24270,0.00,4.00,12.60,4.90 24300,24359,24330,2.20,4.00,17.40,5.50 24360,24419,24390,3.30,4.10,18.60,5.70 24420,24479,24450,4.20,4.10,13.90,5.00 24480,24539,24510,2.40,4.00,9.50,4.50 24540,24599,24570,1.80,4.00,12.90,4.90 24600,24659,24630,2.80,4.00,14.00,5.00 24660,24719,24690,3.60,4.10,11.90,4.80 24720,24779,24750,2.80,4.00,7.20,4.30 24780,24839,24810,1.60,4.00,8.10,4.40 24840,24899,24870,1.50,4.00,8.20,4.40 24900,24959,24930,3.30,4.10,9.80,4.50 24960,25019,24990,3.90,4.10,8.20,4.40 25020,25079,25050,3.80,4.10,6.90,4.30 25080,25139,25110,3.20,4.10,7.30,4.30 25140,25199,25170,2.20,4.00,7.40,4.30 25200,25259,25230,1.00,4.00,6.40,4.20 25260,25319,25290,2.10,4.00,7.50,4.30 25320,25379,25350,3.40,4.10,5.80,4.20 25380,25439,25410,4.50,4.10,8.30,4.40 25440,25499,25470,2.80,4.00,7.10,4.30 25500,25559,25530,2.70,4.00,8.60,4.40 25560,25619,25590,3.10,4.10,9.60,4.50 25620,25679,25650,3.90,4.10,8.70,4.40 25680,25739,25710,3.60,4.10,8.70,4.40 25740,25799,25770,2.90,4.00,8.30,4.40 25800,25859,25830,1.70,4.00,10.20,4.60 25860,25919,25890,2.40,4.00,11.60,4.70 25920,25979,25950,2.20,4.00,11.40,4.70 25980,26039,26010,2.90,4.10,9.40,4.50 26040,26099,26070,3.00,4.10,8.20,4.40 26100,26159,26130,3.60,4.10,8.00,4.40 26160,26219,26190,4.00,4.10,10.80,4.70 26220,26279,26250,3.40,4.10,10.80,4.70 26280,26339,26310,2.20,4.00,9.00,4.50 26340,26399,26370,1.70,4.00,13.60,5.00 26400,26459,26430,2.20,4.00,17.90,5.60 26460,26519,26490,4.10,4.10,19.20,5.80 26520,26579,26550,4.80,4.10,12.90,4.90 26580,26639,26610,3.70,4.10,8.80,4.40 26640,26699,26670,2.50,4.00,9.60,4.50 26700,26759,26730,3.00,4.10,9.90,4.60 26760,26819,26790,5.10,4.20,10.30,4.60 26820,26879,26850,5.50,4.20,9.30,4.50 26880,26939,26910,4.80,4.10,10.00,4.60 26940,26999,26970,3.40,4.10,9.80,4.50 27000,27059,27030,4.20,4.10,10.10,4.60 27060,27119,27090,5.10,4.20,10.70,4.60 27120,27179,27150,5.50,4.20,18.10,5.60 27180,27239,27210,4.70,4.10,20.60,6.00 27240,27299,27270,3.90,4.10,25.10,6.80 27300,27359,27330,4.90,4.10,18.50,5.70 27360,27419,27390,6.40,4.20,17.00,5.50 27420,27479,27450,6.80,4.30,11.40,4.70 27480,27539,27510,5.10,4.20,14.30,5.10 27540,27599,27570,3.20,4.10,20.10,6.00 27600,27659,27630,4.10,4.10,20.20,6.00 27660,27719,27690,5.40,4.20,18.60,5.70 27720,27779,27750,4.20,4.10,14.60,5.10 27780,27839,27810,4.00,4.10,15.50,5.30 27840,27899,27870,3.80,4.10,16.00,5.30 27900,27959,27930,4.50,4.10,16.10,5.30 27960,28019,27990,2.60,4.00,16.00,5.30 28020,28079,28050,1.50,4.00,14.50,5.10 28080,28139,28110,3.60,4.10,15.60,5.30 28140,28199,28170,5.10,4.20,15.60,5.30 28200,28259,28230,6.20,4.20,15.00,5.20 28260,28319,28290,6.40,4.20,15.10,5.20 28320,28379,28350,6.30,4.20,17.60,5.60 28380,28439,28410,5.00,4.20,19.60,5.90 28440,28499,28470,4.00,4.10,17.90,5.60 28500,28559,28530,4.20,4.10,17.70,5.60 28560,28619,28590,5.80,4.20,17.70,5.60 28620,28679,28650,6.60,4.30,17.00,5.50 28680,28739,28710,6.80,4.30,16.60,5.40 28740,28799,28770,6.50,4.20,16.90,5.50 28800,28859,28830,6.20,4.20,17.20,5.50 28860,28919,28890,6.00,4.20,15.40,5.20 28920,28979,28950,6.40,4.20,16.70,5.40 28980,29039,29010,6.40,4.20,18.00,5.60 29040,29099,29070,7.30,4.30,24.80,6.80 29100,29159,29130,6.60,4.30,23.10,6.50 29160,29219,29190,7.20,4.30,25.10,6.80 29220,29279,29250,7.30,4.30,21.50,6.20 29280,29339,29310,8.40,4.40,23.80,6.60 29340,29399,29370,8.50,4.40,23.90,6.60 29400,29459,29430,8.00,4.40,25.60,6.90 29460,29519,29490,7.30,4.30,26.90,7.10 29520,29579,29550,7.40,4.30,25.80,7.00 29580,29639,29610,7.20,4.30,23.20,6.50 29640,29699,29670,7.40,4.30,20.90,6.10 29700,29759,29730,7.50,4.30,21.90,6.30 29760,29819,29790,7.30,4.30,20.60,6.10 29820,29879,29850,7.90,4.40,24.90,6.80 29880,29939,29910,8.70,4.40,24.60,6.70 29940,29999,29970,9.80,4.50,26.30,7.00 30000,30059,30030,10.10,4.60,23.10,6.50 30060,30119,30090,9.50,4.50,23.80,6.60 30120,30179,30150,8.90,4.50,24.50,6.70 30180,30239,30210,8.40,4.40,27.80,7.30 30240,30299,30270,8.80,4.40,35.10,8.70 30300,30359,30330,9.10,4.50,38.60,9.40 30360,30419,30390,9.40,4.50,34.90,8.70 30420,30479,30450,9.00,4.50,26.80,7.10 30480,30539,30510,10.80,4.70,23.40,6.50 30540,30599,30570,12.20,4.80,25.50,6.90 30600,30659,30630,12.80,4.90,25.90,7.00 30660,30719,30690,12.30,4.80,27.50,7.20 30720,30779,30750,11.80,4.80,30.40,7.80 30780,30839,30810,12.30,4.80,30.00,7.70 30840,30899,30870,13.70,5.00,32.00,8.10 30900,30959,30930,13.90,5.00,29.90,7.70 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