Keutsch, Frank Department of Chemistry, University of Wisconsin - Madison MAD-LIP (Madison - Laser Induced Phosphoresence) Glyoxal Instrument BEACHON 2009 date_MST, date in YYYYMMDD time_MST, (fractional day of year in PST at midpoint of measurement, where Jan. 1, 12:00am = 1) mean_TOD_MST, average time of day in seconds since midnight of measurement averaging Altitude_AGL_m, altitude Above Ground Level in meters CHOCHO_pptv, Mixing ratio of glyoxal in pptv CHOCHO_error_pptv, 1 sigma error of mixing ratio of glyoxal in pptv PI_CONTACT_INFO: Address: UW-Madison Dept of Chemistry, 1101 University Ave, Madison WI 53706; email: keutsch@wisc.edu; 608-262-7904 INSTRUMENT_INFO: Tunable Ti:Sapphire Laser Induced Phosphoresence of Gas-Phase Glyoxal DATA_INFO: Raw data was recorded at 1Hz, averaged to 1 minute. DM_CONTACT_INFO: Samuel Henry; UW-Madison Chemistry Dept.; shenry@wisc.edu; 608-262-0269 STIPULATIONS_ON_USE: Do not quote or present without permission. Please contact PI before use. R0: Data has been calibrated and filtered (both for noise and for bad data) as well as instrumental background signal has been subtracted off. Finalized dataset. OTHER_COMMENTS: For absolute concentration error, accuracy and precision errors must be propagated. Diagnostics (cell pressure, temperature, beam power) available upon request. date_HH:MM:SS, time_PST, Altitude_AGL_m, CHOCHO_pptv, CHOCHO_error_pptv 0: 2:30.00,235.00174,1.6,24.1054,3.4098 0: 3:29.00,235.00243,1.6,24.6370,3.7093 0: 4:30.00,235.00313,1.6,23.4969,3.6581 0: 5:30.00,235.00382,1.6,24.7676,2.0266 0: 6:29.00,235.00451,1.6,19.7007,3.2525 0: 9:29.00,235.00660,25.1,32.7833,2.9069 0:10:30.00,235.00729,25.1,28.7262,3.4646 0:11:29.00,235.00799,25.1,27.6835,2.0397 0:12:29.00,235.00868,25.1,28.2478,3.3222 0:13:30.00,235.00938,25.1,29.5636,2.9908 0:14:29.00,235.01007,25.1,26.7387,3.2160 0:16:30.00,235.01146,8.5,26.0964,3.1369 0:17:29.00,235.01215,8.5,23.5071,3.1709 0:18:30.00,235.01285,8.5,25.0149,2.7434 0:19:30.00,235.01354,8.5,25.2288,3.9164 0:20:29.00,235.01424,8.5,22.9024,2.6112 0:21:30.00,235.01493,8.5,24.2178,2.9409 0:24:30.00,235.01701,17.7,29.8435,3.2556 0:25:29.00,235.01771,17.7,27.9676,4.1125 0:26:29.00,235.01840,17.7,28.7161,2.4507 0:27:30.00,235.01910,17.7,32.0653,3.3013 0:28:29.00,235.01979,17.7,31.4256,3.3242 0:29:29.00,235.02049,17.7,25.9326,3.5173 0:31:29.00,235.02187,1.6,29.9711,3.0029 0:32:30.00,235.02257,1.6,20.5117,2.6926 0:33:30.00,235.02326,1.6,23.9729,2.6514 0:34:29.00,235.02396,1.6,25.4893,2.9480 0:35:30.00,235.02465,1.6,19.0677,2.2505 0:36:30.00,235.02535,1.6,26.4323,3.2936 0:39:29.00,235.02743,25.1,26.9498,3.6560 0:40:29.00,235.02812,25.1,29.1271,2.8836 0:41:30.00,235.02882,25.1,30.5795,2.3245 0:42:29.00,235.02951,25.1,22.8585,2.9701 0:43:29.00,235.03021,25.1,23.2712,3.4559 0:44:30.00,235.03090,25.1,23.6385,2.7226 0:46:30.00,235.03229,8.5,27.1887,3.4744 0:47:30.00,235.03299,8.5,31.9434,3.1301 0:48:29.00,235.03368,8.5,25.9409,3.3297 0:49:30.00,235.03438,8.5,26.2190,3.4178 0:50:30.00,235.03507,8.5,28.4068,2.1861 0:51:29.00,235.03576,8.5,28.1380,3.1986 0:54:29.00,235.03785,17.7,23.1738,4.1930 0:55:30.00,235.03854,17.7,26.8968,3.5603 0:56:29.00,235.03924,17.7,25.7167,2.6558 0:57:29.00,235.03993,17.7,25.7943,3.3687 0:58:30.00,235.04063,17.7,24.5107,3.0563 0:59:29.00,235.04132,17.7,21.7559,3.5222 1: 1:30.00,235.04271,1.6,30.0864,3.6127 1: 2:29.00,235.04340,1.6,22.0157,3.2095 1: 3:30.00,235.04410,1.6,27.1980,2.8169 1: 4:30.00,235.04479,1.6,25.6651,3.3404 1: 5:29.00,235.04549,1.6,25.9309,2.3645 1: 6:30.00,235.04618,1.6,25.2548,3.0207 1: 9:30.00,235.04826,25.1,22.9433,3.2830 1:10:29.00,235.04896,25.1,30.1585,3.9277 1:11:29.00,235.04965,25.1,24.0402,2.2970 1:12:30.00,235.05035,25.1,26.0741,3.3254 1:13:29.00,235.05104,25.1,22.3097,2.8495 1:14:29.00,235.05174,25.1,20.9335,3.4735 1:16:29.00,235.05312,8.5,26.8895,3.4160 1:17:30.00,235.05382,8.5,34.9951,3.0479 1:18:30.00,235.05451,8.5,31.3226,3.3076 1:19:29.00,235.05521,8.5,22.1018,3.4934 1:20:30.00,235.05590,8.5,25.3138,2.4764 1:21:30.00,235.05660,8.5,22.8691,2.9149 1:24:29.00,235.05868,17.7,28.3606,3.1862 1:25:29.00,235.05937,17.7,21.3116,3.6897 1:26:30.00,235.06007,17.7,26.5972,2.2049 1:27:29.00,235.06076,17.7,29.7824,3.2742 1:28:30.00,235.06146,17.7,23.4032,3.7643 1:29:30.00,235.06215,17.7,22.5678,3.5745 1:31:30.00,235.06354,1.6,23.1769,2.9395 1:32:30.00,235.06424,1.6,19.1999,3.4292 1:33:29.00,235.06493,1.6,21.3647,2.9513 1:34:30.00,235.06563,1.6,27.0165,3.2825 1:35:30.00,235.06632,1.6,21.9234,2.4789 1:36:29.00,235.06701,1.6,21.2027,3.1385 1:39:29.00,235.06910,25.1,25.0589,2.6911 1:40:30.00,235.06979,25.1,26.7872,3.2452 1:41:29.00,235.07049,25.1,30.0508,2.5482 1:42:29.00,235.07118,25.1,29.6071,3.6474 1:43:30.00,235.07188,25.1,29.5169,2.7228 1:44:29.00,235.07257,25.1,27.5923,4.0696 1:46:30.00,235.07396,8.5,30.5792,3.2695 1:47:29.00,235.07465,8.5,28.7402,3.8073 1:48:30.00,235.07535,8.5,28.4702,3.4237 1:49:30.00,235.07604,8.5,27.4813,3.0158 1:50:29.00,235.07674,8.5,26.6210,2.2991 1:51:30.00,235.07743,8.5,23.2987,3.3270 1:54:30.00,235.07951,17.7,22.5369,2.9740 1:55:29.00,235.08021,17.7,29.7800,2.6111 1:56:29.00,235.08090,17.7,27.1405,2.5589 1:57:30.00,235.08160,17.7,24.1205,4.1696 1:58:29.00,235.08229,17.7,21.8008,3.0803 1:59:29.00,235.08299,17.7,22.7982,3.2693 2: 1:29.00,235.08437,1.6,23.2902,3.2528 2: 2:30.00,235.08507,1.6,24.6994,3.6485 2: 3:30.00,235.08576,1.6,29.0173,3.1694 2: 4:29.00,235.08646,1.6,25.0735,2.6662 2: 5:30.00,235.08715,1.6,26.3646,2.3684 2: 6:30.00,235.08785,1.6,20.8840,3.2900 2: 9:29.00,235.08993,25.1,30.8885,3.3904 2:10:29.00,235.09062,25.1,26.7535,3.2560 2:11:30.00,235.09132,25.1,29.7612,2.4504 2:12:29.00,235.09201,25.1,30.9097,3.1127 2:13:29.00,235.09271,25.1,31.2581,3.0906 2:14:30.00,235.09340,25.1,32.8162,3.5866 2:16:30.00,235.09479,8.5,27.4887,2.6707 2:17:30.00,235.09549,8.5,30.6433,2.8331 2:18:29.00,235.09618,8.5,31.1184,3.3425 2:19:30.00,235.09688,8.5,33.7863,3.0682 2:20:30.00,235.09757,8.5,33.0095,2.1128 2:21:29.00,235.09826,8.5,26.7037,3.0768 2:24:29.00,235.10035,17.7,28.4453,3.7529 2:25:30.00,235.10104,17.7,34.1048,3.6511 2:26:29.00,235.10174,17.7,32.7203,2.1687 2:27:29.00,235.10243,17.7,23.1228,3.2159 2:28:30.00,235.10313,17.7,28.0026,3.7087 2:29:29.00,235.10382,17.7,27.1349,3.6739 2:31:30.00,235.10521,1.6,26.5155,3.3490 2:32:29.00,235.10590,1.6,25.3798,3.3466 2:33:30.00,235.10660,1.6,25.8692,3.6065 2:34:30.00,235.10729,1.6,21.8404,3.2134 2:35:29.00,235.10799,1.6,21.0740,2.2624 2:36:30.00,235.10868,1.6,18.3472,3.1351 2:39:30.00,235.11076,25.1,21.4805,3.1598 2:40:29.00,235.11146,25.1,26.6409,3.8361 2:41:29.00,235.11215,25.1,23.1008,2.3494 2:42:30.00,235.11285,25.1,20.9755,2.7610 2:43:29.00,235.11354,25.1,22.2087,3.8134 2:44:29.00,235.11424,25.1,24.4624,3.5433 2:46:29.00,235.11562,8.5,29.7633,3.3308 2:47:30.00,235.11632,8.5,29.0141,3.2777 2:48:30.00,235.11701,8.5,25.4227,3.4840 2:49:29.00,235.11771,8.5,28.0608,2.8698 2:50:30.00,235.11840,8.5,30.1567,2.2116 2:51:30.00,235.11910,8.5,31.4986,3.1814 2:54:29.00,235.12118,17.7,27.8994,2.9487 2:55:29.00,235.12187,17.7,27.8727,3.2997 2:56:30.00,235.12257,17.7,27.1378,2.3322 2:57:29.00,235.12326,17.7,25.9324,3.6177 2:58:30.00,235.12396,17.7,27.2264,3.2618 2:59:30.00,235.12465,17.7,26.4368,3.7345 3: 1:30.00,235.12604,1.6,25.1281,2.7196 3: 2:30.00,235.12674,1.6,23.8231,3.1698 3: 3:29.00,235.12743,1.6,29.3538,2.9219 3: 4:30.00,235.12813,1.6,27.0993,2.8743 3: 5:30.00,235.12882,1.6,21.4327,2.2440 3: 6:29.00,235.12951,1.6,25.9307,2.8303 3: 9:29.00,235.13160,25.1,28.6251,3.7559 3:10:30.00,235.13229,25.1,25.7339,3.2658 3:11:29.00,235.13299,25.1,29.0000,2.8355 3:12:29.00,235.13368,25.1,25.0778,3.1765 3:13:30.00,235.13438,25.1,25.2208,3.6914 3:14:29.00,235.13507,25.1,29.7442,2.9206 3:16:30.00,235.13646,8.5,26.1065,3.1600 3:17:29.00,235.13715,8.5,29.9087,2.9211 3:18:30.00,235.13785,8.5,24.9036,2.8989 3:19:30.00,235.13854,8.5,31.5404,2.8690 3:20:29.00,235.13924,8.5,31.7842,2.4835 3:21:30.00,235.13993,8.5,25.5041,2.9904 3:24:30.00,235.14201,17.7,27.6999,3.1479 3:25:29.00,235.14271,17.7,29.1286,3.3571 3:26:29.00,235.14340,17.7,27.7999,1.9641 3:27:30.00,235.14410,17.7,29.9884,3.2360 3:28:29.00,235.14479,17.7,24.0929,2.6252 3:29:29.00,235.14549,17.7,22.6980,3.8788 3:31:29.00,235.14687,1.6,27.6572,3.6796 3:32:30.00,235.14757,1.6,21.0950,2.8639 3:33:30.00,235.14826,1.6,25.0153,3.6318 3:34:29.00,235.14896,1.6,21.1487,3.2203 3:35:30.00,235.14965,1.6,25.1151,2.3097 3:36:30.00,235.15035,1.6,19.3565,3.1198 3:39:29.00,235.15243,25.1,29.1482,3.1685 3:40:29.00,235.15312,25.1,32.1447,3.2120 3:41:30.00,235.15382,25.1,20.9090,2.0646 3:42:29.00,235.15451,25.1,24.4111,2.9725 3:43:29.00,235.15521,25.1,26.3159,3.2796 3:44:30.00,235.15590,25.1,24.0813,3.0018 3:46:30.00,235.15729,8.5,28.8853,3.3512 3:47:30.00,235.15799,8.5,19.3810,3.4214 3:48:29.00,235.15868,8.5,26.4966,4.1897 3:49:30.00,235.15938,8.5,24.4699,3.5770 3:50:30.00,235.16007,8.5,29.1738,2.4275 3:51:29.00,235.16076,8.5,22.5530,3.4476 3:54:29.00,235.16285,17.7,26.0885,3.0809 3:55:30.00,235.16354,17.7,29.1494,3.8931 3:56:29.00,235.16424,17.7,28.8975,2.4517 3:57:29.00,235.16493,17.7,21.2362,3.8607 3:58:30.00,235.16563,17.7,25.3568,3.6730 3:59:29.00,235.16632,17.7,28.9483,3.8136 4: 1:30.00,235.16771,1.6,17.0947,4.1166 4: 2:29.00,235.16840,1.6,22.2124,3.3572 4: 3:30.00,235.16910,1.6,19.3949,2.9043 4: 4:30.00,235.16979,1.6,23.5975,3.0981 4: 5:29.00,235.17049,1.6,18.8075,2.2238 4: 6:30.00,235.17118,1.6,25.3654,3.6460 4: 9:30.00,235.17326,25.1,24.2154,3.0507 4:10:29.00,235.17396,25.1,29.1282,3.2266 4:11:29.00,235.17465,25.1,27.1391,1.9732 4:12:30.00,235.17535,25.1,27.1158,3.8004 4:13:29.00,235.17604,25.1,26.8054,3.6346 4:14:29.00,235.17674,25.1,24.5211,2.8811 4:16:29.00,235.17812,8.5,34.9410,3.6127 4:17:30.00,235.17882,8.5,33.6071,3.6460 4:18:30.00,235.17951,8.5,27.9930,3.7089 4:19:29.00,235.18021,8.5,22.8637,3.7294 4:20:30.00,235.18090,8.5,25.0550,2.4841 4:21:30.00,235.18160,8.5,25.1475,3.7623 4:24:29.00,235.18368,17.7,24.9028,3.4107 4:25:29.00,235.18437,17.7,25.4254,3.7890 4:26:30.00,235.18507,17.7,25.7716,2.5912 4:27:29.00,235.18576,17.7,23.8471,3.1693 4:28:30.00,235.18646,17.7,24.8064,3.1934 4:29:30.00,235.18715,17.7,20.1360,2.8209 4:31:30.00,235.18854,1.6,23.8598,3.5296 4:32:30.00,235.18924,1.6,23.9421,2.9803 4:33:29.00,235.18993,1.6,22.3594,2.5306 4:34:30.00,235.19063,1.6,28.2426,3.2977 4:35:30.00,235.19132,1.6,22.8764,2.3487 4:36:29.00,235.19201,1.6,19.0239,2.9108 4:39:29.00,235.19410,25.1,31.0649,2.8322 4:40:30.00,235.19479,25.1,25.0742,3.2013 4:41:29.00,235.19549,25.1,24.5485,2.1200 4:42:29.00,235.19618,25.1,24.9146,3.6777 4:43:30.00,235.19688,25.1,21.6756,3.0194 4:44:29.00,235.19757,25.1,25.4772,2.6902 4:46:30.00,235.19896,8.5,30.9018,3.1685 4:47:29.00,235.19965,8.5,32.3658,3.4955 4:48:30.00,235.20035,8.5,23.1610,2.8195 4:49:30.00,235.20104,8.5,29.7635,2.5786 4:50:29.00,235.20174,8.5,24.8015,1.9915 4:51:30.00,235.20243,8.5,20.2991,2.9637 4:54:30.00,235.20451,17.7,27.2555,3.2742 4:55:29.00,235.20521,17.7,30.4252,3.4084 4:56:29.00,235.20590,17.7,24.6789,2.2346 4:57:30.00,235.20660,17.7,27.5060,3.4842 4:58:29.00,235.20729,17.7,22.4482,3.2075 4:59:29.00,235.20799,17.7,23.6645,2.9331 5: 1:29.00,235.20937,1.6,29.6649,2.7595 5: 2:30.00,235.21007,1.6,26.7626,2.8561 5: 3:30.00,235.21076,1.6,23.8110,3.4307 5: 4:29.00,235.21146,1.6,25.0612,2.5361 5: 5:30.00,235.21215,1.6,21.7075,1.8496 5: 6:30.00,235.21285,1.6,20.4629,3.4408 5: 9:29.00,235.21493,25.1,28.8613,3.3962 5:10:29.00,235.21562,25.1,27.2526,3.2811 5:11:30.00,235.21632,25.1,26.1489,2.2190 5:12:29.00,235.21701,25.1,23.9208,2.9747 5:13:29.00,235.21771,25.1,24.5057,3.0087 5:14:30.00,235.21840,25.1,28.1073,3.4633 5:16:30.00,235.21979,8.5,30.5625,2.9178 5:17:30.00,235.22049,8.5,26.4719,2.5080 5:18:29.00,235.22118,8.5,25.9933,3.0796 5:19:30.00,235.22188,8.5,27.6006,3.3070 5:20:30.00,235.22257,8.5,23.8288,2.1221 5:21:29.00,235.22326,8.5,24.1499,3.1542 5:24:29.00,235.22535,17.7,22.2530,3.5988 5:25:30.00,235.22604,17.7,26.9048,3.9006 5:26:29.00,235.22674,17.7,30.1963,2.4616 5:27:29.00,235.22743,17.7,27.0441,3.1668 5:28:30.00,235.22813,17.7,27.3395,3.0630 5:29:29.00,235.22882,17.7,23.7577,2.9831 5:31:30.00,235.23021,1.6,22.5960,3.3993 5:32:29.00,235.23090,1.6,22.3704,2.6216 5:33:30.00,235.23160,1.6,26.0449,3.5570 5:34:30.00,235.23229,1.6,22.6947,2.9500 5:35:29.00,235.23299,1.6,22.6225,2.3270 5:36:30.00,235.23368,1.6,23.0824,3.0931 5:39:30.00,235.23576,25.1,23.3073,3.1310 5:40:29.00,235.23646,25.1,28.3489,3.6038 5:41:29.00,235.23715,25.1,21.6897,2.4036 5:42:30.00,235.23785,25.1,27.9124,3.3256 5:43:29.00,235.23854,25.1,27.2799,3.4506 5:44:29.00,235.23924,25.1,23.7785,2.9573 5:46:29.00,235.24062,8.5,29.5241,3.0201 5:47:30.00,235.24132,8.5,31.6346,3.5431 5:48:30.00,235.24201,8.5,25.0775,3.0577 5:50:30.00,235.24340,8.5,24.1119,3.5107 5:51:30.00,235.24410,8.5,31.4221,3.8347 5:54:29.00,235.24618,17.7,27.7532,3.3176 5:55:29.00,235.24687,17.7,23.9213,3.8786 5:56:30.00,235.24757,17.7,29.6257,2.5632 5:57:29.00,235.24826,17.7,27.3343,3.3976 5:58:30.00,235.24896,17.7,23.9181,2.8843 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